In situ time resolved synchrotron powder diffraction study of thaumasite     

Annalisa Martucci  Giuseppe Cruciani 《Physics and Chemistry of Minerals》2006,33(10):723-731

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.  相似文献   

A Practical Procedure for the Measurement of Fragmentation by Blasting by Image Analysis   总被引：1，自引：0，他引：1  

J. A. Sanchidrián  P. Segarra  L. M. López 《Rock Mechanics and Rock Engineering》2006,39(4):359-382

Summary. The operation of a digital image analysis system in a limestone quarry is described. The calibration of the system, required in order to obtain moderately reliable fragmentation values, is done from muckpile sieving data by tuning the image analysis software settings so that the fragmentation curve obtained matches as close as possible the sieving. The sieving data have also been used to extend the fragment size distribution curves measured to sizes below the system’s optical resolution and to process the results in terms of fragmented rock, discounting the material coming from a loose overburden (natural fines) that is cast together with the fragmented rock. Automatic and manual operation modes of the image analysis are compared. The total fragmentation of a blast is obtained from the analysis of twenty photographs; a criterion for the elimination of outlier photographs has been adopted using a robust statistic. The limitations of the measurement system due to sampling, image processing and fines corrections are discussed and the errors estimated whenever possible. An analysis of consistency of the results based on the known amount of natural fines is made. Blasts with large differences in the amount of fines require a differentiated treatment, as the fine sizes tend to be the more underestimated in the image analysis as they become more abundant; this has been accomplished by means of a variable fines adjustment factor. Despite of the unavoidable errors and the large dispersion always associated with large-scale rock blasting data, the system is sensitive to relative changes in fragmentation.  相似文献   

Alteration, evaluation and use of extremaduran granite residues     

C. Albarrán-Liso  M. M. Jordán-Vidal  T. Sanfeliu-Montolio  M. J. Liso-Rubio 《Environmental Geology》2006,49(7):1043-1050

The necessity of eliminating debris from a granite quarry has awakened an interest in applications of by-products, called “marginal arids”, in different fields, like construction and foundations for roadways, restoration, material for the manufacture of artificial rocks, and artesian products etc. Conclusions obtained from the results of tests carried out by X-ray diffraction of granite quarry by-products in Extremadura, Spain, submitted to different treatments, are established. Test pieces from two quarries are analyzed and compared generally and specifically, for commercial use. Finally, conclusions relating to essays in test pieces and mineral dynamics of marginal arid granite are exposed.  相似文献   

The effect of composition and cation ordering on the compressibility of columbites up to 7 GPa     

M. Pistorino  F. Nestola  T. Boffa Ballaran  M. C. Domeneghetti 《Physics and Chemistry of Minerals》2006,33(8-9):593-600

The unit-cell parameters of two columbite samples along the (Fe,Mn)Nb₂O₆ solid solution were measured by means of high-pressure single-crystal X-ray diffraction up to pressures of 7 GPa. The compressional behaviour of these minerals was studied as a function of composition and degree of order. The P–V data of all the samples were fitted with a third-order Birch–Murnaghan equation of state. For the two samples with different compositions but identical degree of order the substitution of Mn for Fe causes a decrease of the bulk modulus K _T0, from 153(1) to 146(1) GPa, without any effect on the pressure first derivative K′. For the two samples with the same composition, cation ordering causes an increase of the bulk modulus from 149(1) to 153(1) GPa and of the pressure first derivative from 4.1(2) to 4.8(3). The compressional behaviour is anisotropic with a linear axial compressibility scheme β _b > β _c ≥ β _a for all samples, regardless of composition and degree of order. Such anisotropy increases sligthly with increasing Mn content.  相似文献   

额济纳绿洲沙尘暴沉积特征     

温小浩  李保生  王为  LI Sen  OU Xianjiao  ZHENG Yanming 《地理学报(英文版)》2006,16(4):502-508

1 Introduction Oases are unique ecosystems and important residences for our ancestors in arid and semiarid regions of the world, and have deeply been imprinted by human actions, such as Jericho oasis of Jordan Valley, Jarmo oasis of the Euphrates River an…  相似文献   

川中丘陵区土壤颗粒分形特征     

林正雨邓良基  高雪松 《山地学报》2006,24(B10):120-125

分析了27个紫色土丘陵区土壤样品的机械组成，运用分形模型计算出土壤颗粒分形维数D（D=2．817—3．030），探讨了分形维数D与土壤粒度组成、土壤抗蚀性之间的关系，并分析了不同土地利用方式下土壤颗粒分形维数D与土壤有机质含量（O．M）、土壤容重（B.D）的相关关系。研究表明：土壤颗粒分形维数D能够很好的表征土壤质地，重点反映〈0．05mm的细颗粒物质，尤其是粘粒，其次是粉粒；与土壤有机质含量（O．M）、土壤容重（B．D）均达到极显著水平；其次分形维数D还能作为评价土壤水土流失和土壤生态恢复的指标。  相似文献   

大气CO2浓度升高对土壤中不同粒级碳的影响   总被引：4，自引：0，他引：4  

马红亮朱建国  谢祖彬刘钢 曾青 《亚热带资源与环境学报》2006,1(1):33-40

不同粒级土壤中的碳有着不同的周转规律，在高CO2浓度条件下，它们含量的变化将在一定程度上反映土壤碳是累积还是减少，对明确土壤碳的变化趋势有重要意义．采用田间培养试验初步模拟研究在高CO2浓度条件下土壤不同粒级碳的分布．结果表明，加入秸秆培养1年，由于CO2浓度升高的原因导致在低氮（LN）、常规氮（NN）和高氮（HN）水平下土壤中碳分别增加0．01、1．10、1．22g／kg，表现为粒级〈53μm土壤颗粒中碳分别增加1．53、2．19、2．70g／kg．粒级〈53μmm土壤颗粒碳量的增加，主要是由于其重量分配百分数显著增加36．2％，碳浓度增加5．4％；粒级〉250μm和250～53μm土壤颗粒部分虽然其碳浓度分别增加20．8％和17．3％（P〈0．05），怛由于重量分配百分数分别显著降低22．8％和36．1％，结果碳量降低．试验表明高CO2浓度导致不同粒级土壤的分配及碳浓度的变化；高氮施肥水平下有增加土壤碳量特别是小粒级土壤碳量的趋势．  相似文献   

Influence of sedimentary environments on mechanical properties of clastic rocks     

Zhaoping Meng  Jincai Zhang  Suping Peng 《Environmental Geology》2006,51(1):113-120

The sedimentary environments are the intrinsic factor controlling the mechanical properties of clastic rocks. Examining the relationship between rock sedimentary environments and rock mechanical properties gives a better understanding of rock deformation and failure mechanisms. In this study, more than 55 samples in coal measures were taken from seven different lithologic formations in eastern China. Using the optical microscope the sedimentary characteristics, such as components of clastic rocks and sizes of clastic grains were quantitatively tested and analyzed. The corresponding mechanical parameters were tested using the servo-controlled testing system. Different lithologic attributes in the sedimentary rocks sampled different stress–strain behaviors and failure characteristics under different confining pressures, mainly due to different compositions and textures. Results demonstrate that clastic rocks have the linear best-fit for Mohr-Coulomb failure criterion. The elastic moduli in clastic rocks are highly dependent upon confining pressures, unlike hard rocks. The envelope lines of the mechanical properties versus the contents of quartz, detritus of the grain diameter of more than 0.03 mm, and grain size in clastic rocks are given. The compressive strength or elastic modulus and the grain diameter have a non-monotonic relation and demonstrate the “grain-diameter softening” effect.  相似文献   

利用激光强度信息分类激光扫描测高数据   总被引：21，自引：0，他引：21  

刘经南  张小红 《武汉大学学报(信息科学版)》2005,30(3):189-193

三维机载激光扫描测高数据中不仅含有每个激光脚点的位置和高程信息，而且越来越多的系统同时能提供激光脚点回波信号的强度信息。不同反射面介质对激光信号的反射特性不一样．用实测的数据对激光回波信号的强度信息进行统计标定，并基于标定结果．实现了联合激光强度信息和高程信息进行分类的算法．获得了较为满意的结果。  相似文献   

微量相X射线衍射定量分析的一种简便方法     

何泽能李振山  斯永敏 《岩矿测试》2005,24(2):81-86

阐述了关于微量相X射线衍射定量分析的一种简便方法———近似线性关系法,它适用于二相体系(或基体吸收系数基本恒定的多相体系)材料中微量相的定量分析。该方法不需要在待测样品中加入参考物相,分析时仅需对一条衍射线进行测定,因而分析时间很短,其测定结果与实际含量的相对误差为-10.2%～ 21.4%,与外标法和内标法的测量结果的精度相当。  相似文献